Charge transport and diffusion of ionic liquids in nanoporous silica membranes

Citations Over TimeTop 11% of 2010 papers

Abstract

Charge transport in 1-hexyl-3-methylimidazolium hexafluorophosphate ionic liquid in oxidized nanoporous silicon membranes is investigated in a wide frequency and temperature range by a combination of Broadband Dielectric Spectroscopy (BDS) and Pulsed Field Gradient Nuclear Magnetic Resonance (PFG NMR). By applying the Einstein-Smoluchowski relations to the dielectric spectra, diffusion coefficient is obtained in quantitative agreement with independent PFG NMR measurements. More than 10-fold systematic decrease in the effective diffusion coefficient from the bulk value is observed in hydrophilic silica nanopores. A model assuming a reduced mobility at the pore-matrix interface is shown to provide a quantitative explanation for the remarkable decrease of effective transport quantities (such as diffusion coefficient, dc conductivity and consequently, the dielectric loss) of the ionic liquid in non-silanized membranes. This approach is supported by the observation that silanization of porous silica membranes results in a significant increase of the effective diffusion coefficient, which approaches the value for the bulk liquid.

Related Papers

• → Two-dimensional diffusion time correlation experiment using a single direction gradient(2014)13 cited
• → Biodegradable Ionic Liquids: Selected Synthetic Applications(2007)36 cited
• → Manganese Dioxide Allylic and Benzylic Oxidation Reactions in Ionic Liquids(2004)25 cited
• → Formation of Nanoporous Structure on Pt Plate Surface by Alloying/Dealloying Technique(2011)4 cited
• → Nanoporous Metal Template Methods(2022)