Electron induced dissociation (EID) tandem mass spectrometry of octaethylporphyrin and its iron(iii) complex
Chemical Communications2010Vol. 47(1), pp. 418–420
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Abstract
EID tandem mass spectrometry of singly-charged electrosprayed ions of octaethylporphyrin (OEP) and its iron(III) complex results in ionisation to give doubly-charged precursor and fragment ions. Singly-charged fragments are also observed. EID fragmentation differs significantly to that observed in electron ionisation mass spectrometry.
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