On the relationship between structure and reaction rate in olefin ring-closing metathesis
Chemical Communications2010Vol. 46(38), pp. 7145–7145
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Ian W. Ashworth, Davide Carboni, Ian H. Hillier, David J. Nelson, Jonathan M. Percy, Giuseppe Rinaudo, Mark A. Vincent
Abstract
In the RCM reactions of a series of simple α,ω-dienes, the relative order of reactivity has been unambiguously determined showing that cyclohexene forms faster than cyclopentene or cycloheptene. 1,5-Hexadiene inhibits the RCM of 1,7-octadiene; 1,5-hexadiene cannot progress to the RCM product (cyclobutene) but forms an unexpectedly stable cyclic η(2)-complex.
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