Dual modification of a triple-stranded β-helix nanotube with Ru and Re metal complexes to promote photocatalytic reduction of CO2
Chemical Communications2011Vol. 47(7), pp. 2074–2074
Citations Over TimeTop 14% of 2011 papers
Norihiko Yokoi, Yuki Miura, Chen-Yuang Huang, Nobuyuki Takatani, Hiroshi Inaba, Tomomi Koshiyama, Shuji Kanamaru, Fumio Arisaka, Yoshihito Watanabe, Susumu Kitagawa, Takafumi Ueno
Abstract
We have constructed a robust β-helical nanotube from the component proteins of bacteriophage T4 and modified this nanotube with Ru(II)(bpy)(3) and Re(I)(bpy)(CO)(3)Cl complexes. The photocatalytic system arranged on the tube catalyzes the reduction of CO(2) with higher reactivity than that of the mixture of the monomeric forms.
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