Rapid, quantitative, and site specific synthesis of biomolecular radicals from a simple photocaged precursor
Chemical Communications2011Vol. 47(10), pp. 2835–2835
Citations Over TimeTop 14% of 2011 papers
Abstract
Novel p-iodobenzoate-based labelling reagents are shown to be effective photocaged precursors for synthesizing biomolecular radicals site-selectively in the gaseous and condensed phases. In vacuo, a single pulse of UV photons (266 nm) is sufficient to quantitatively photolyse the C-I bond. In aqueous solutions, the photolysis half-life is estimated to be 2.5 minutes when irradiating with a 15 W compact fluorescent lamp (254 nm).
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