Epoxidation of alkenes and oxidation of alcohols with hydrogen peroxide catalyzed by a manganese(v) nitrido complex
Chemical Communications2011Vol. 47(14), pp. 4273–4273
Citations Over TimeTop 10% of 2011 papers
Abstract
The manganese(V) nitrido complex (PPh(4))(2)[Mn(N)(CN)(4)] is an active catalyst for alkene epoxidation and alcohol oxidation using H(2)O(2) as an oxidant. The catalytic oxidation is greatly enhanced by the addition of just one equivalent of acetic acid. The oxidation of ethene by this system has been studied computationally by the DFT method.
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