A four coordinate parent imidevia a titanium nitridyl
Chemical Communications2011Vol. 48(10), pp. 1529–1531
Citations Over TimeTop 14% of 2011 papers
Ba L. Tran, M.P. Washington, Danielle A. Henckel, Xinfeng Gao, Hyunsoo Park, Maren Pink, Daniel J. Mindiola
Abstract
Treatment of d(1) [(nacnac)TiCl(Ntol(2))] with NaN(3) results in NaCl formation and N(2) ejection to yield the first four coordinate, parent imide [(nacnac)Ti=NH(Ntol(2))] (nacnac(-)=[ArNC(CH(3))](2)CH, Ar = 2,6-iPr(2)C(6)H(3), tol = 4-CH(3)C(6)H(4)).
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