Electrocatalytic reduction of CO2 to CO by polypyridyl ruthenium complexes
Chemical Communications2011Vol. 47(47), pp. 12607–12607
Citations Over TimeTop 10% of 2011 papers
Zuofeng Chen, Chuncheng Chen, David R. Weinberg, Peng Kang, Javier J. Concepcion, Daniel P. Harrison, Maurice Brookhart, Thomas J. Meyer
Abstract
Electrocatalytic reduction of CO(2) by [Ru(tpy)(bpy)(solvent)](2+) (tpy = 2,2':6',2''-terpyridine, bpy = 2,2'-bipyridine) and its structural analogs is initiated by sequential 1e(-) reductions at the tpy and bpy ligands followed by rate limiting CO(2) addition to give a metallocarboxylate intermediate. It undergoes further reduction and loss of CO.
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