Hierarchical cooperative binary ionic porphyrin nanocomposites
Chemical Communications2012Vol. 48(40), pp. 4863–4863
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Yongming Tian, Tito Busani, G. Uyeda, Kathleen E. Martin, Frank van Swol, Craig J. Medforth, Gabriel A. Montaño, John A. Shelnutt
Abstract
Cooperative binary ionic (CBI) solids comprise a versatile new class of opto-electronic and catalytic materials consisting of ionically self-assembled pairs of organic anions and cations. Herein, we report CBI nanocomposites formed by growing nanoparticles of one type of porphyrin CBI solid onto a second porphyrin CBI substructure with complementary functionality.
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