Approaching a stable, green twisted heteroacene through “clean reaction” strategy
Chemical Communications2012Vol. 48(48), pp. 5974–5974
Citations Over TimeTop 1% of 2012 papers
Gang Li, Hieu M. Duong, Zhonghan Zhang, Jinchong Xiao, Lei Liu, Yanli Zhao, Hua Zhang, Fengwei Huo, Shuzhou Li, Jan Ma, Fred Wudl, Qichun Zhang
Abstract
A new, longest, stable, green twisted heteroacene 2-methyl-1,4,6,13-tetraphenyl-7:8,11:12-bisbenzo-anthro[g]isoquinolin-3(2H)-one (3) was synthesized by employing a "clean reaction" strategy based on thermally eliminating lactam bridges. Calculation shows that the HOMO-LUMO bandgap is in good agreement with experimental data.
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