Formation of a surface covalent organic framework based on polyester condensation
Chemical Communications2012Vol. 48(54), pp. 6779–6779
Citations Over TimeTop 10% of 2012 papers
Antonela C. Marele, Rubén Mas‐Ballesté, Luigi Terracciano, Jonathan Rodríguez‐Fernández, Isadora Berlanga, Simone S. Alexandre, Roberto Otero, José M. Gallego, Félix Zamora, José M. Gómez‐Rodríguez
Abstract
The reaction between 1,3,5-tris(4-hydroxyphenyl)benzene and benzene-1,3,5-tricarbonyl trichloride leads to polyester condensation and formation of a novel COF on an Au(111) surface. The characterization performed in situ by means of variable temperature STM and XPS reveals the formation of an array of hexagonal cavities with ca. 2 nm size.
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