Crystal structure and carrier transport properties of a new semiconducting 2D coordination polymer with a 3,5-dimethylpiperidine dithiocarbamate ligand
Chemical Communications2012Vol. 49(39), pp. 4316–4318
Citations Over TimeTop 10% of 2012 papers
Takashi Okubo, Haruho Anma, Naoya Tanaka, Kento Himoto, Shu Seki, Akinori Saeki, Masahiko Maekawa, Takayoshi Kuroda‐Sowa
Abstract
A novel mixed-valence Cu(I)-Cu(II) coordination polymer with an infinite two-dimensional structure, [Cu3(I)Cu(II)Br3(3,5-Dmpip-dtc)2]n (3,5-Dmpip-dtc(-) = 3,5-dimethylpiperidine dithiocarbamate), was prepared, and its structure was characterized by X-ray diffraction. It shows semiconducting behavior with a relatively small activation energy and high carrier mobility, which were investigated using impedance spectroscopy and flash photolysis time-resolved microwave conductivity measurements, respectively.
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