Crystal structure of a luminescent thiolated Ag nanocluster with an octahedral Ag64+core
Chemical Communications2012Vol. 49(3), pp. 300–302
Citations Over TimeTop 10% of 2012 papers
Abstract
A yellow luminescent thiolate-protected Ag(14)(SC(6)H(3)F(2))(12)(PPh(3))(8) cluster was synthesized and structurally characterized by single-crystal X-ray analysis. The cluster contains an octahedral Ag(6)(4+) unit encapsulated by eight cubically arranged [Ag(+)(SC(6)H(3)F(2)(-))(2)PPh(3)] tetrahedra that share one corner (i.e. SC(6)H(3)F(2)(-)) between them.
Related Papers
- → Chapter 2 Structures and Mineralogy of Clay Minerals(2006)431 cited
- → Flexible Vertex Engineers the Controlled Assembly of Distorted Supramolecular Tetrahedral and Octahedral Cages(2022)13 cited
- → Structure and luminescence of Cs2WO2F4: Efficient luminescence of isolated [WO2F4]−2 octahedra(1992)23 cited
- → (1,10-phen)2Mo3O9: a new one-dimensional organic/inorganic hybrid material consisting of two {MoO4N2} octahedra and one {MoO4} tetrahedron alternately(2000)15 cited
- → Ideal wollastonite and the structural relationship between the pyroxenoids and pyroxenes(2016)8 cited