Investigation of Zr(iv) and 89Zr(iv) complexation with hydroxamates: progress towards designing a better chelator than desferrioxamine B for immuno-PET imaging
Chemical Communications2012Vol. 49(10), pp. 1002–1004
Citations Over TimeTop 10% of 2012 papers
François Guérard, Yong Sok Lee, Raphaël Tripier, Lawrence P. Szajek, Jeffrey R. Deschamps, Martin W. Brechbiel
Abstract
Single crystal X-ray diffraction shows that Zr(iv) forms an octa-coordinated complex with 4 bidentate hydroxamates whose solution structures were investigated by utilizing density functional theory at the level of B3LYP/DGDZVP. Stability constants obtained by potentiometry were in accordance with the tendency observed when radiolabeling with (89)Zr.
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