A redox-active luminescent ytterbium based single molecule magnet
Chemical Communications2012Vol. 49(6), pp. 615–617
Citations Over TimeTop 10% of 2012 papers
Fabrice Pointillart, Boris Le Guennic, Stéphane Golhen, Olivier Cador, Olivier Maury, Lahcène Ouahab
Abstract
A redox active dinuclear complex [Yb(tta)(2)(L(1))(L(2))](2)·1.4(CH(2)Cl(2)) displays single molecule magnet behaviour with M(J) = ±7/2 ground state. The anisotropic barrier Δ is evaluated by the three dc data fit, ac analysis and emission spectrum demonstrating the correlation between magnetic and optical properties.
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