A single-molecule magnet assembly exhibiting a dielectric transition at 470 K
Chemical Science2012Vol. 3(12), pp. 3366–3366
Citations Over TimeTop 10% of 2012 papers
Yu‐Xia Wang, Wei Shi, Li Han, You Song, Liang Fang, Yanhua Lan, Annie K. Powell, Wolfgang Wernsdorfer, Liviu Ungur, Liviu F. Chibotaru, Mingrong Shen, Peng Cheng
Abstract
A triangular Dy(III) single-molecule magnet (SMM) exhibiting ferroelectric bistability is assembled in an acentric space group Pna21. Hysteresis loops associated with its SMM behavior together with a two-step slow relaxation of the magnetization are observed below 30 K. A transition with dielectric anomalies between a paraelectric and a ferroelectric phase occurs at 470 K.
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