Oxygen vacancy ordering in superlatives of the two novel oxides, La2Ni2O5 and La2Co2O5, prepared by low temperature reduction of the parent perovskites
Journal of the Chemical Society Chemical Communications1985Iss. 1, pp. 7–7
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Abstract
Controlled reduction of LaBO3(B = Co or Ni) perovskites gives rise to ordered structures of composition La2B2O5, belonging to the homologous series LanBnO3n–1, which retain the original features of the perovskite; the co-ordination of the transition metal ions differ, with Ni2+ ions showing octahedral and square-planar co-ordination and the Co2+ ions showing octahedral and tetrahedral co-ordination.
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