Solvent dependent reductive defluorination of aliphatic C–F bonds employing Sm(HMDS)2
Chemical Communications2013Vol. 49(18), pp. 1826–1826
Citations Over TimeTop 10% of 2013 papers
Abstract
Sm(HMDS)(2) in n-hexane mediates fast cleavage of primary, secondary and tertiary alkyl fluorides in good to excellent yields. In n-hexane Sm(HMDS)(2) exhibits uniquely enhanced reductive ability towards the C-F bond compared to when using THF as solvent.
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