From a supramolecular tetranitrile to a porous covalent triazine-based framework with high gas uptake capacities
Chemical Communications2013Vol. 49(38), pp. 3961–3961
Citations Over TimeTop 1% of 2013 papers
Abstract
Transformation of tetra(4-cyanophenyl)ethylene under Lewis acidic (ZnCl2) conditions at 400 °C leads to the formation of a porous covalent triazine-based organic framework (CTF) with a high surface area (2235 m(2) g(-1)), high CO2 and CH4 uptakes and the highest hydrogen uptake for a CTF material (1.86 wt% at 77 K, 1 bar).
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