Ionic conductivity of [Li+@C60](PF6−) in organic solvents and its electrochemical reduction to Li+@C60˙−
Chemical Communications2013Vol. 49(67), pp. 7376–7376
Citations Over TimeTop 17% of 2013 papers
Hiroshi Ueno, Ken Kokubo, Yuji Nakamura, Kei Ohkubo, Naohiko Ikuma, Hiroshi Moriyama, Shunichi Fukuzumi, Takumi Oshima
Abstract
The ionic conductivity of [Li(+)@C60](PF6(-)) was measured in o-dichlorobenzene, and found to be higher than that of TBA(+)PF6(-). Electrochemical reduction of [Li(+)@C60](PF6(-)) without any supporting electrolyte gave the monovalent radical anion Li(+)@C60˙(-), as confirmed by the characteristic ESR signal and NIR absorption band.
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