Development of an expedient intramolecular Pauson–Khand reaction approach to stereoselectively construct the trans-decalin with a C1 quaternary chiral center
Chemical Communications2013Vol. 49(78), pp. 8806–8806
Citations Over TimeTop 16% of 2013 papers
Abstract
Stereoselective synthesis of the trans-decalin subunit with a defined C1 quaternary chiral center has been achieved by the Pauson-Khand reaction (PKR) as a key step. The developed chemistry offers an alternative to the IMDA reaction that has been used for the syntheses of trans-decalin based biologically active natural products.
Related Papers
- → Effect of Hydrogen Donor Addition on Thermal Decomposition of Bio-jet Fuel(2021)4 cited
- Effects of Reaction Conditions on Saturated Hydrogenation of Naphthalene(2009)
- → Od ESR spectra of cis-decalin radical cations in liquid and glassy solutions(1986)29 cited
- → Synthesis of cis-decalin derivative via π-allylpalladium intermediate and its transformation to usefully functionalized trans-decalin derivative(1992)13 cited