Na+/K+ switch of enantioselectivity in G-quadruplex DNA-based catalysis
Chemical Communications2013Vol. 49(95), pp. 11161–11161
Citations Over TimeTop 14% of 2013 papers
Abstract
Here we found that the enantioselectivity of G-quadruplex DNA-based Diels-Alder reaction can be switched by just changing Na(+) to K(+), which is ascribed to the structural transformation of the G-quadruplex from antiparallel to hybrid-type. By tuning the ratio of Na(+)/K(+), the enantioselectivity of the Diels-Alder reaction could be switchable and shows much more sensitive to K(+) than to Na(+).
Related Papers
- → Arrangements of human telomere DNA quadruplex in physiologically relevant K + solutions(2009)199 cited
- → Fluorescent Sensor for Monitoring Structural Changes of G-Quadruplexes and Detection of Potassium Ion(2009)119 cited
- → Folding pathways of human telomeric hybrid G-quadruplex structure(2007)22 cited
- → Recognize three different human telomeric G-quadruplex conformations by quinacrine(2012)16 cited
- → Expression of Concern: The Truncated Human Telomeric Sequence forms a Hybrid‐Type Intramolecular Mixed Parallel/antiparallel G‐quadruplex Structure in K+ Solution(2016)2 cited