Au144−xPdx(SR)60 nanomolecules
Chemical Communications2013Vol. 49(92), pp. 10850–10850
Citations Over TimeTop 10% of 2013 papers
Abstract
Au144-xPdx(SR)60 alloy nanomolecules were synthesized and characterized by ESI mass spectrometry to atomic precision. The number of Pd atoms can be varied by changing the incoming metal ratio and plateaus at 7 Pd atoms. Based on the proposed 3-shell structure of Au144(SR)60, we hypothesize that the Pd atoms are selectively incorporated into the central Au12 icosahedral core.
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