High-rate synthesis of Cu–BTC metal–organic frameworks
Chemical Communications2013Vol. 49(98), pp. 11518–11518
Citations Over TimeTop 10% of 2013 papers
Ki‐Joong Kim, Yong Jun Li, Peter B. Kreider, Chih‐Hung Chang, Nick Wannenmacher, Praveen K. Thallapally, Ho‐Geun Ahn
Abstract
The reaction conditions for the synthesis of Cu-BTC (BTC = benzene-1,3,5-tricarboxylic acid) were elucidated using a continuous-flow microreactor-assisted solvothermal system to achieve crystal size and phase control. A high-rate synthesis of Cu-BTC metal-organic frameworks with a BET surface area of more than 1600 m(2) g(-1) (Langmuir surface area of more than 2000 m(2) g(-1)) and with a 97% production yield could be achieved with a total reaction time of 5 minutes.
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