Synthesis of the 6,6,5,7-tetracyclic core of daphnilongeranin B
Chemical Communications2013Vol. 50(40), pp. 5294–5294
Citations Over TimeTop 10% of 2013 papers
Abstract
An efficient approach toward the synthesis of the 6,6,5,7-tetracyclic core of the daphnilongeranin B, a Daphniphyllum alkaloid, is reported. The bridged 6,6-bicyclic system was constructed using a gold(i) catalysed Conia-ene reaction, while the 5- and 7-membered rings were assembled by two diastereoselective Michael addition reactions, respectively.
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