Synthesis of a guanidine NHC complex and its application in borylation reactions
Chemical Communications2014Vol. 50(33), pp. 4344–4346
Citations Over TimeTop 10% of 2014 papers
Chia‐Cheng Tai, Ming‐Shiuan Yu, Yilin Chen, Wen‐Hang Chuang, Ting‐Hua Lin, Glenn P. A. Yap, Tiow‐Gan Ong
Abstract
Synthesis of guanidine-linked NHC can be achieved easily and its copper complexes were isolated and fully characterized. These Cu complexes are found to be versatile catalysts for hydroboration, semihydrogenation and carboboration of alkynes in a highly stereo- and regioselective fashion.
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