A metal-free dyotropic-like rearrangement of 2-oxa allylic alcohols in the presence of organoboronic acids
Chemical Communications2014Vol. 50(69), pp. 9879–9882
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Abstract
The first example of a dyotropic-like rearrangement of 2-oxa allylic alcohols in the presence of catalytic amounts of Selectfluor and DABCO was reported, which provides a facile access to organoboronates. This reaction represents an unprecedented dyotropic rearrangement consisting of cleavage of two vicinal bonds (one C-C bond and one C=C bond).
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