Isoselective ring-opening polymerization of rac-lactide initiated by achiral heteroscorpionate zwitterionic zinc complexes
Chemical Communications2014Vol. 50(77), pp. 11411–11411
Citations Over TimeTop 10% of 2014 papers
Abstract
A highly isotactic stereoblock PLA has been obtained using the achiral heteroscorpionate zwitterionic zinc complexes as catalysts, for the first time, via a chain-end control mechanism.
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