A robust and modular synthesis of ynamides
Chemical Communications2014Vol. 51(16), pp. 3316–3319
Citations Over TimeTop 10% of 2014 papers
Abstract
A flexible, modular ynamide synthesis is reported that uses trichloroethene as an inexpensive two carbon synthon. A wide range of amides and electrophiles can be converted to the corresponding ynamides, importantly including acyclic carbamates, hindered amides, and aryl amides. This method thus overcomes many of the limitations of other approaches to this useful functionality.
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