Tetrazine functionalized zirconium MOF as an optical sensor for oxidizing gases
Chemical Communications2014Vol. 51(12), pp. 2280–2282
Citations Over TimeTop 10% of 2014 papers
Abstract
Dihydro-1,2,4,5-tetrazine-3,6-dicarboxylate was introduced into the chemically stable UiO-66 structure by a postsynthetic linker exchange reaction to create an optical sensor material for the detection of oxidative agents such as nitrous gases. The incorporated tetrazine unit can be reversibly oxidized and reduced, which is accompanied by a drastic colour change from yellow to pink and vice versa. The high stability of the framework during redox reaction was proven by powder X-ray diffraction and nitrogen physisorption measurements.
Related Papers
- → 1,2,4,5-tetrazine based energetic materials(1999)225 cited
- → Controlling the Polymorphism and Topology Transformation in Porphyrinic Zirconium Metal–Organic Frameworks via Mechanochemistry(2019)108 cited
- → Overview of Syntheses and Molecular-Design Strategies for Tetrazine-Based Fluorogenic Probes(2021)49 cited
- → The role of 1,2,4,5-tetrazine rings in π–π stacking interactions(2003)41 cited
- → A tetrazine-fused aggregation induced emission luminogen for bioorthogonal fluorogenic bioprobe(2021)28 cited