Rh(iii)-catalyzed C–H activation/cyclization of benzamides and diazo compounds to form isocoumarins and α-pyrones
Chemical Communications2014Vol. 51(12), pp. 2380–2383
Citations Over TimeTop 10% of 2014 papers
Abstract
Rhodium-catalyzed intermolecular cyclization of benzamides and diazo compounds via C-H activation has been achieved to construct C-C/C-O bonds for the first time. The process provides a facile approach for the construction of isocoumarins and α-pyrones without the need for high temperature or adding oxidants.
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