Organometallic polyphosphorus and -arsenic ligands as linkers between pre-assembled linear CuI fragments
Chemical Communications2015Vol. 51(14), pp. 2893–2895
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M. Fleischmann, Luis Dütsch, Mehdi Elsayed Moussa, A. Schindler, Gábor Balázs, Christophe Lescop, Manfred Scheer
Abstract
A simple and straightforward synthesis of a new linear trinuclear Cu(I) cluster with polyphosphine ligands is presented. The reaction of this pre-organized Cu3 precursor with En ligand complexes (E = P, As; n = 2, 5) affords discrete complexes exhibiting end-on η(1)-coordination of the E2 ligands or one-dimensional coordination polymers featuring σ-1,3-bridging E5 rings, respectively.
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