Nickel-catalyzed thiolation of unactivated aryl C–H bonds: efficient access to diverse aryl sulfides
Chemical Communications2015Vol. 51(19), pp. 4069–4072
Citations Over TimeTop 1% of 2015 papers
Abstract
A nickel-catalyzed thiolation of unactivated C(sp(2))-H bonds with disulfides employing the PIP directing group was described. This process uses a catalytic nickel catalyst and no metallic oxidants or cocatalysts are required. The reaction tolerates various important functional groups and heteroarenes, providing an efficient synthetic pathway to access diverse diaryl sulfides.
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