Active site engineering in UiO-66 type metal–organic frameworks by intentional creation of defects: a theoretical rationalization
CrystEngComm2014Vol. 17(2), pp. 395–406
Citations Over TimeTop 10% of 2014 papers
Matthias Vandichel, Julianna Hajek, Frederik Vermoortele, Michel Waroquier, Dirk De Vos, Véronique Van Speybroeck
Abstract
The catalytic activity of the Zr-benzenedicarboxylate (Zr-BDC) UiO-66 increases by using synthesis modulators as trifluoroacetate (TFA) or hydrochloric acid (HCl), which can be removed post-synthetically.
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