Growth rates and water stability of 2D boronate ester covalent organic frameworks
Chemical Communications2015Vol. 51(35), pp. 7532–7535
Citations Over TimeTop 10% of 2015 papers
Abstract
We examine the growth rates, activation energies, and hydrolytic stability of multiple 2D boronate ester covalent organic frameworks by turbidity measurements, observing a 200-fold range in stability. The rate-determining step in boronate ester 2D COF growth is not in-solution condensation, but rather interlayer polymer stacking through a nucleation-elongation process.
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