Hybrid uranyl–vanadium nano-wheels
Chemical Communications2015Vol. 51(50), pp. 10134–10137
Citations Over TimeTop 14% of 2015 papers
Ganna A. Senchyk, Ernest M. Wylie, S. Prizio, Jennifer E. S. Szymanowski, Ginger E. Sigmon, Peter C. Burns
Abstract
Hybrid uranyl-vanadium oxide clusters intermediate between transition metal polyoxometalates and uranyl peroxide cage clusters were obtained by dissolving uranyl nitrate in the ionic liquid 3-ethyl-1-methylimidazolium ethyl sulfate mixed with an aqueous solution containing vanadium. Where sulfate was present, wheel-shaped {U20V20} crystallized and contains ten sulfate tetrahedra, and in the absence of added sulfate, {U2V16}, a derivative of {V18}, was obtained.
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