Synthesis of nanocrystals of Zr-based metal–organic frameworks with csq-net: significant enhancement in the degradation of a nerve agent simulant
Chemical Communications2015Vol. 51(54), pp. 10925–10928
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Peng Li, Rachel C. Klet, Su‐Young Moon, Timothy C. Wang, Pravas Deria, Aaron W. Peters, Benjamin M. Klahr, Hea Jung Park, Salih S. Al‐Juaid, Joseph T. Hupp, Omar K. Farha
Abstract
The synthesis of nano-sized particles of NU-1000 (length from 75 nm to 1200 nm) and PCN-222/MOF-545 (length from 350 nm to 900 nm) is reported. The catalytic hydrolysis of methyl paraoxon was investigated as a function of NU-1000 crystallite size and a significant enhancement in the rate was observed for the nano-sized crystals compared to microcrystals.
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