Charge control of the inverse trans-influence
Chemical Communications2015Vol. 51(93), pp. 16671–16674
Citations Over TimeTop 18% of 2015 papers
Henry S. La Pierre, Michael W. Rosenzweig, Boris Kosog, Christina Hauser, Frank W. Heinemann, Stephen T. Liddle, Karsten Meyer
Abstract
The synthesis and characterization of uranium(VI) mono(imido) complexes, by the oxidation of corresponding uranium(V) species, are presented. These experimental results, paired with DFT analyses, allow for the comparison of the electronic structure of uranium(VI) mono(oxo) and mono(imido) ligands within a conserved ligand framework and demonstrate that the magnitude of the ground state stabilization derived from the inverse trans-influence (ITI) is governed by the relative charge localization on the multiply bonded atom or group.
Related Papers
- → Substituent effects on the charge-transfer band shifts in 9,10-dihydro-9,10-o-benzenoanthracene-1,4-diones : further confirmation of the charge-transfer transition for a symmetry-forbidden charge-transfer interaction(1982)18 cited
- → A stable binuclear complex containing PdHPd bonds(1984)36 cited
- → Charge-coupled devices with compensated charge transfer(2000)
- Advances of Cr(III) based catalysts for 1-hexene production(2010)
- → The $m$-weak core inverse(2023)