Deuteration enhances catalyst lifetime in palladium-catalysed alcohol oxidation
Chemical Communications2015Vol. 52(10), pp. 2189–2191
Citations Over TimeTop 15% of 2015 papers
Nicola Armenise, Nabil Tahiri, Niek N. H. M. Eisink, Mathieu Denis, Manuel Jäger, Johannes G. de Vries, Martin D. Witte, Adriaan J. Minnaard
Abstract
The catalyst palladium/2,9-CD3-phenanthroline has a 1.8 times higher turnover number than its non-deuterated counterpart in the aerobic alcohol oxidation of methyl glucoside and allows the regioselective oxidation with dioxygen as the terminal oxidant.
Related Papers
- → Recent Advances in the Regioselective Synthesis of Pyrazoles(2011)73 cited
- → Perfectly Regioselective and Sequential Protection of Glucopyranosides(2010)53 cited
- → Remote substituent effects on regioselectivity in the Pauson–Khand reaction of 2-substituted norbornenes(2001)19 cited
- → Highly chemo/regioselective alkoxycarbonylation of terminal allenes catalyzed by Ru/N-ligand system(2023)3 cited
- → β-Aminoenones in the regioselective synthesis of 1,3,5-trialkylpyrazoles. The influence of the substituents in the mechanism and the regioselectivity of the reaction(1998)12 cited