Cuprophilic interactions in highly luminescent dicopper(i)–NHC–picolyl complexes – fast phosphorescence or TADF?
Chemical Communications2016Vol. 52(14), pp. 2932–2935
Citations Over TimeTop 10% of 2016 papers
Jörn Nitsch, Frederick Lacemon, Andreas Lorbach, Antonius Eichhorn, Federico Cisnetti, Andreas Steffen
Abstract
This case study on a series of monomeric, dimeric and polymeric Cu(I) chlorido NHC-picolyl complexes shows that cuprophilic interactions can ensure strong spin-orbit coupling for fast (reverse)intersystem-crossing T1 ↔ S1 and T1 → S0, and therefore can serve as a design motif for the construction of highly efficient Cu(I)-based TADF or T1 emitters.
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