Controlling the stereoselectivity of rac-LA polymerization by chiral recognition induced the formation of homochiral dimeric metal alkoxides
Polymer Chemistry2016Vol. 7(11), pp. 2022–2036
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Paweł Horeglad, Martyna Cybularczyk‐Cecotka, A. Litwińska, Anna Maria Dąbrowska, Maciej Dranka, Grażyna Z. Żukowska, Mateusz Urbańczyk, Michał Michalak
Abstract
Chiral recognition of monomeric Me2MOR units resulting in the formation of homochiral dimeric species [Me2M(μ-OR)]2(M = Ga, In), leads to heteroselective catalysts for the ring opening polymerization ofrac-lactide (rac-LA).
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