C–H arylations of 1,2,3-triazoles by reusable heterogeneous palladium catalysts in biomass-derived γ-valerolactone
Chemical Communications2016Vol. 52(63), pp. 9777–9780
Citations Over TimeTop 1% of 2016 papers
Xu Tian, Fanzhi Yang, Dace Rasiņa, Michaela Bauer, Svenja Warratz, Francesco Ferlin, Luigi Vaccaro, Lutz Ackermann
Abstract
C-H arylations were accomplished with a user-friendly heterogeneous palladium catalyst in the biomass-derived γ-valerolactone (GVL) as an environmentally-benign reaction medium. The user-friendly protocol was characterized by ample substrate scope and high functional group tolerance in the C-H arylation of 1,2,3-triazoles, and the palladium catalyst could be recycled and reused in the C-H activation process.
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