Record-high thermal barrier of the relaxation of magnetization in the nitride clusterfullerene Dy2ScN@C80-Ih
Chemical Communications2017Vol. 53(56), pp. 7901–7904
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D. S. Krylov, Fupin Liu, Stanislav M. Avdoshenko, Lukas Spree, Bruno Weise, Anja Waske, A. U. B. Wolter, B. Büchner, Alexey A. Popov
Abstract
The Dy-Sc nitride clusterfullerene Dy2ScN@C80-Ih exhibits slow relaxation of magnetization up to 76 K. Above 60 K, thermally-activated relaxation proceeds via the fifth-excited Kramers doublet with the energy of 1735 ± 21 K, which is the highest barrier ever reported for dinuclear lanthanide single molecule magnets.
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