Gold-catalyzed [2+2+2+2]-annulation of 1,3,5-hexahydro-1,3,5-triazines with alkoxyallenes
Chemical Communications2017Vol. 53(95), pp. 12770–12773
Citations Over TimeTop 13% of 2017 papers
Abstract
An unprecedented gold-catalyzed [2+2+2+2]-annulation of 1,3,5-hexahydro-1,3,5-triazines with alkoxyallenes has been developed, providing eight-membered heterocycles in good to excellent yields. Deuterium labeling and control experiments reveal the possible reaction mechanism for this annulation.
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