(Ge2P2)2−: a binary analogue of P4as a precursor to the ternary cluster anion [Cd3(Ge3P)3]3−
Chemical Communications2017Vol. 54(12), pp. 1421–1424
Citations Over TimeTop 16% of 2017 papers
Stefan Mitzinger, Jascha Bandemehr, Kevin Reiter, J. Scott McIndoe, Xiulan Xie, Florian Weigend, John F. Corrigan, Stefanie Dehnen
Abstract
The novel binary P4 analogue (Ge2P2)2- proved to be a suitable precursor for heteroatomic cluster synthesis. Over time in solution, it rearranges to form (Ge7P2)2-, as shown by NMR studies and X-ray diffraction. Reactions of (Ge2P2)2- with CdPh2 afford [K(crypt-222)]3[Cd3(Ge3P)3], containing an unprecedented ternary cluster anion with a triangular Cd3 moiety.
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