Dechlorination of chlorobenzene on vanadium-based catalysts for low-temperature SCR
Chemical Communications2018Vol. 54(16), pp. 2032–2035
Citations Over TimeTop 10% of 2018 papers
Abstract
Chlorobenzene (CB) inhibits SCR activity of V-based catalysts at low temperature, though the adsorption amount is small. NH3 adsorption increases due to the break in the C-Cl bond during CB oxidation. The dissociated Cl- ions provide extra Brønsted acid sites, leading to the formation of inactive NH4Cl. Ce and Mn improve dechlorination, forming more NH4Cl on the catalyst surface.
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