Tri(o-tolyl)phosphine for highly efficient Suzuki coupling of propargylic carbonates with boronic acids
Chemical Communications2018Vol. 54(74), pp. 10451–10454
Citations Over TimeTop 17% of 2018 papers
Abstract
A highly efficient catalytic system consisting of Pd2(dba)3·CHCl3 and tri(o-tolyl)phosphine has been identified for the coupling of propargylic carbonates with different types of organo boronic acids at room temperature. Excellent central-to-axial chirality transfer was also demonstrated.
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