Cu-catalyzed regioselective borylcyanation of 1,3-dienes
Chemical Communications2018Vol. 54(91), pp. 12832–12835
Citations Over TimeTop 10% of 2018 papers
Abstract
Catalytic regioselective generation of an allyl-Cu complex through Cu-B(pin) (pin = pinacolato) addition to 1,3-dienes followed by reaction with an electrophilic cyanation reagent to afford multifunctional organoboron compounds is presented. Reactions of a wide range of 1,3-dienes with different substitution patterns promoted by an easily accessible phosphine-Cu complex proceed with high yields and regioselectivity.
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