Calcium vanadate sub-microfibers as highly reversible host cathode material for aqueous zinc-ion batteries
Chemical Communications2019Vol. 55(16), pp. 2265–2268
Citations Over TimeTop 10% of 2019 papers
Xu Liu, Huang Zhang, Dorin Geiger, Jin Han, Alberto Varzi, Ute Kaiser, Arianna Moretti, Stefano Passerini
Abstract
For the first time, CaV6O16·3H2O (CVO), synthesized via a highly efficient and fast microwave reaction, is used as a cathode material for aqueous zinc-ion batteries. Ex situ X-ray diffraction confirms the structure of this material to be stable upon reversible Zn2+ intercalation, due to its large interlayer distance (8.08 Å). The pillaring effect of calcium makes the as-prepared CVO an excellent Zn2+ cation host.
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