Ultrafast charge transfer excited state dynamics in trifluoromethyl-substituted iridium(iii) complexes
Physical Chemistry Chemical Physics2018Vol. 20(43), pp. 27256–27260
Citations Over TimeTop 17% of 2018 papers
Robin Bevernaegie, Lionel Marcélis, Angélica Moreno Betancourt, Baptiste Laramée‐Milette, Garry S. Hanan, Frédérique Loiseau, Michel Sliwa, Benjamin Elias
Abstract
Time-resolved spectroscopy was exploited to gain new insights into the nature and dynamics of charge transfer excited states of bis-cyclometalated Ir(iii) complexes. We showed that its dynamics is strongly influenced by the nature of the diimine ligand due to the existence of a ligand-ligand charge transfer process in the picosecond timescale. All the results are supported by DFT/TD-DFT calculations and spectroelectrochemistry.
Related Papers
- → Color tunable phosphorescent light-emitting diodes based on iridium complexes with substituted 2-phenylbenzothiozoles as the cyclometalated ligands(2004)80 cited
- → Pentahydridobis(Tricyclohexylphosphine)‐Iridium(V) and Trihydridotris(Triphenylphos‐phine)Iridium(III)(1998)10 cited
- → Molecular Engineering of Iridium Complexes and their Application in Organic Light Emitting Devices(2007)6 cited